Using percentages with dynamic charts makes it easy to analyze changes as values adjust. 

The minimum value for an axis must be a whole number, which can be an issue when using percentages as you may want the scale to go from 0.5 (50%) to 0.9 (90%) for example.

You can do this by plotting the numbers multiplied by 100, and then setting the number format of the axis to display the% sign after the number using the format 0"%".

This means the scale starts at a whole number and the axis labelling is also correct.

If you need more precision, you can also use a format like 0.00"%".

As the axis is scaled by 100 you must also scale the values being plotted. If you are creating a small multiple against a cube the easiest way to do this is to create a custom calculation with the expression

 [Measures].[My Measure] * 100 

and plot that.